Ben Affleck and fiancee Jennifer Lopez, wearing Harry Winston jewelry, attends the 75th Annual Academy Awards at the Kodak Theater on March 23, 2003 in Hollywood, California. (Photo by Kevin Winter/Getty Images)

As we look forward to the 2022 Academy Awards this Sunday, we’re taking a look at the most memorable Oscars couples moments through the years. With iconic duos like Elizabeth Taylor and Richard Burton, Jennifer Anniston and Brad Pitt, and Jada Pinkett Smith and Will Smith (to name a few), all stepping out in glam and coordinated looks, each couple created buzzy, unforgettable red carpet moments that went down in pop culture history.

Below, we’re taking a trip down memory lane looking back at our favorite pairings on the carpet.

Elizabeth Taylor and Richard Burton, 1970

Married actors Elizabeth Taylor and Richard Burton (1925 – 1984) attend the Academy Awards ceremonies, Los Angeles, California, April 7, 1970. (Photo by Frank Edwards/Fotos International/Getty Images)

The Cleopatra costars attended the Academy Awards together in 1970.

Sonny and Cher, 1973

Sonny Bono And Cher (Photo by Ron Galella/Ron Galella Collection via Getty Images)

Married from 1967 to 1978, Cher and then-husband Sonny Bono of Sonny & Cher “I’ve Got You Babe” fame attended the 1973 Academy Awards arm-in-arm.

Anjelica Huston and Jack Nicholson, 1975

Jack Nicholson and Anjelica Huston at the Dorothy Chandler Pavilion in Los Angeles, California, 8th April 1975. Photo by Michael Ochs Archives/Getty Images)

Dating on-and-off for 17 years, Jack Nicholson and Anjelica Huston attended the Oscars together in 1975 early on in their relationship.

Cher and Val Kilmer, 1984

American actors Cher and Val Kilmer arrive at the 56th Academy Awards, where Cher is nominated for Best Supporting Actress in Silkwood. (Photo by Bill Nation/Sygma via Getty Images)

Cher and actor Val Kilmer walked the carpet in 1983, 1984 and 1995 – and reportedly remain friends to this day.

Cindy Crawford and Richard Gere, 1991

Richard Gere and Cindy Crawford at the Shrine Auditorium in Los Angeles, California (Photo by Ron Galella/Ron Galella Collection via Getty Images)

Married from 1991 to 1995, supermodel Cindy Crawford and actor Richard Gere attended the Oscars hand-in-hand for three consecutive years, beginning in 1991 when Crawford wore a plunging red Versace gown.

Madonna and Michael Jackson, 1991

Madonna and Michael Jackson (Photo by Ron Galella/Ron Galella Collection via Getty Images)

Madonna and the King of Pop Michael Jackson attended the ’91 Oscars together, when Madonna performed “Sooner or Later (I Always Get My Man)” during the show dressed in a Marilyn Monroe-inspired Bob Mackie creation.

Rita Wilson and Tom Hanks, 1995

Tom Hanks & Rita Wilson during The 67th Annual Academy Awards – Arrivals at Shrine Auditorium in Los Angeles, California, United States. (Photo by KMazur/WireImage)

Married since 1988, actors Rita Wilson and Tom Hanks are the ultimate Hollywood power couple.

Gwyneth Paltrow and Brad Pitt, 1996

Gwyneth Paltrow & Brad Pitt (Photo by Barry King/WireImage)

The two Se7en costars walked the carpet in ’96, a year before calling it quits.

Jada Pinkett Smith and Will Smith, 1997

Jada Pinkett Smith and Will Smith during The 69th Annual Academy Awards – Arrivals at Shrine Auditorium in Los Angeles, California, United States. (Photo by Jim Smeal/Ron Galella Collection via Getty Images)

Married since 1997 and together to this day, Jada Pinkett Smith and Will Smith are Oscars red carpet staples.

Nicole Kidman and Tom Cruise, 1997

Actress Nicole Kidman and actor Tom Cruise attend the 69th Annual Academy Awards on March 24, 1997 at Shrine Auditorium in Los Angeles, California. (Photo by Ron Galella, Ltd./Ron Galella Collection via Getty Images)

During their marriage from 1990 to 2001, Nicole Kidman and then-husband Tom Cruise were Oscars red carpet regulars.

Anne Heche and Ellen DeGeneres, 1999

Actress Anne Heche and partner Ellen DeGeneres attend The 71st Annual Academy Awards – Arrivals on March 21, 1999 at the Dorothy Chandler Pavilion in Los Angeles, California. (Photo by Ron Davis/Getty Images)

Actress Anne Heche and Ellen DeGeneres coordinated in a sparkly white gown, and white suit, respectively.

Drew Barrymore and Edward Norton, 1999

Drew Barrymore & Edward Norton during 71st Annual Academy Awards – Arrivals at Dorothy Chandler Pavilion in Los Angeles, California, United States. (Photo by SGranitz/WireImage)

Drew Barrymore and Edward Norton attended the ceremony together when he was nominated for Best Actor for his role in American History X.  

Jennifer Anniston and Brad Pitt, 2000

Jennifer Aniston and Brad Pitt at the Morton’s Restaurant in Los Angeles, CA (Photo by Rob Beccaris/WireImage)

Married from 2000 to 2005, Jennifer Anniston and Brad Pitt looked sharp in all black at the 2000 Oscars.

Jennifer Lopez and Ben Affleck, 2003

HOLLYWOOD – MARCH 23: Actors Ben Affleck and fiancee Jennifer Lopez, wearing Harry Winston jewelry, attends the 75th Annual Academy Awards at the Kodak Theater on March 23, 2003 in Hollywood, California. (Photo by Kevin Winter/Getty Images)

Bennifer walked the Oscars red carpet in 2003 amid their short-lived engagement. Together from 2002-2004, they rekindled their romance in 2021.

Leonardo DiCaprio and Gisele Bündchen, 2005

Leonardo DiCaprio, nominee Best Actor in a Leading Role for ?The Aviator?, and Gisele Bundchen at the Kodak Theatre in Hollywood, California (Photo by Kevin Mazur/WireImage)

Typically in attendance with his mother, Leonardo DiCaprio brought along then-girlfriend supermodel Gisele Bündchen to the 2005 Oscars, with whom he dated on and off for six years from 1999 to 2005.

Beyoncé and Jay-Z, 2005

Beyonce and Jay-Z during The 77th Annual Academy Awards – Red Carpet at Kodak Theatre in Hollywood, California, United States. (Photo by KMazur/WireImage)

Married since 2008, the couple made their first Oscars appearance in 2005.

Javier Bardem and Penélope Cruz, 2011

Actors Javier Bardem and Penelope Cruz arrive at the 83rd Annual Academy Awards held at the Kodak Theatre on February 27, 2011 in Hollywood, California.

The lovebirds are set to make another glam appearance at the 2022 ceremony, with Bardem up for Best Lead Actor for his role in Being the Ricardos, and Cruz up for Best Lead Actress for her portrayal in Parallel Mothers.